AIIMS2014Chemistry-Carboxylic acids

AIIMS 2014 Chemistry Carboxylic acids MCQ Question

Type: MCQ-conceptual-Medium-Class 12

Which of the following carboxylic acids undergoes decarboxylation easily?

A

C6H5COCOOH

B

C6H5COCH2COOH

C

C6H5CHOHCOOH

D

C6H5CHCOOH NH2

Correct Answer

Option B

Detailed Explanation

The correct answer is B) C6H5COCH2COOH because it contains a carbonyl group adjacent to the carboxylic acid, which stabilizes the resulting carbanion during the decarboxylation process. This stabilization through resonance facilitates the loss of carbon dioxide (CO2), making the decarboxylation reaction more favorable compared to the other options, which lack this structural feature.

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