AIIMS2014Chemistry-Aldehyde reactions

AIIMS 2014 Chemistry Aldehyde reactions MCQ Question

Type: MCQ-conceptual-Medium-Class 12

C3H6O did not give a silver mirror with Tollen’s reagent, but gave an oxime with hydroxylamine. It can give positive

A

iodoform test

B

Fehling’s test

C

Schiff’s test

D

carbylamines test

Correct Answer

Option A

Detailed Explanation

The compound C3H6O is likely a ketone, as it does not react with Tollen's reagent (which indicates the absence of an aldehyde) but does form an oxime with hydroxylamine, suggesting the presence of a carbonyl group. Ketones can give a positive iodoform test if they have a methyl group adjacent to the carbonyl, which is the case for some ketones, making option A the correct answer. In contrast, the other tests mentioned (Fehling's, Schiff's, and carbylamines) are primarily used for aldehydes or specific amines, not ketones.

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