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AIIMS2019Chemistry-Thermodynamics

AIIMS 2019 Chemistry Hess's Law MCQ Question

Type: MCQ-numerical-Medium-Class 11

Here is the extracted question and its options formatted for your frontend and database.Rendered TextQuestion 98:If Boiling point of water is 100∘C100^\circ\text{C}. How much gram of NaCl\text{NaCl} is added in 500 g500\text{ g} of water to increase the boiling point of water by approx. 1∘C1^\circ\text{C}. (Kb)H2O=0.52 K⋅kg/mole(K_b)_{\text{H}_2\text{O}} = 0.52\text{ K}\cdot\text{kg/mole}

A

2.182 g2.182\text{ g}

B

28.12 g28.12\text{ g}

C

14.06 g14.06\text{ g}

D

7.03 g7.03\text{ g}

Correct Answer

Option B

Detailed Explanation

To derive the formation reaction of C₂H₅OH(l), the enthalpy changes from reactions (I), (II), and (III) are manipulated according to Hess's law. By multiplying reaction (I) by 2 and reaction (II) by 3, and then adding these to reaction (III), the total enthalpy change is calculated as ΔH = [–393 kJ mol⁻¹ × 2] + [–287.3 kJ mol⁻¹ × 3] + 1366.8 kJ mol⁻¹, resulting in ΔH = –281.1 kJ mol⁻¹ for the formation of C₂H₅OH(l). Other options are not applicable as they do not provide relevant enthalpy values or calculations related to the formation reaction.

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