AIIMS2019Chemistry-Thermodynamics

AIIMS 2019 Chemistry Gas Laws Assertion Reason Question

Type: Assertion Reason-conceptual-Medium-Class 11

Assertion : The graph between P\text{P} v/s 1V\frac{1}{\text{V}} is a straight line.

Reason : The anionic sites occupied by unpaired electrons (due to F-centres)

A

Both assertion and reason are true and reason is the correct explanation of assertion.

B

Both assertion and reason are true but reason is not the correct explanation of assertion.

C

Assertion is true but reason is false.

D

Both assertion and reason are false.

Correct Answer

Option B

Detailed Explanation

The assertion is true because Boyle's law accurately describes the inverse relationship between pressure (P) and volume (V) at constant temperature (T), represented as P ∝ 1/V. However, the reason provided is false because while the adiabatic process is indeed described by the equation PVᵞ = constant, it does not explain Boyle's law, which applies under isothermal conditions. Option A is incorrect because the reason does not correctly explain the assertion, while option C is incorrect as it misrepresents the truth of the assertion. Option D is also incorrect since the assertion is valid.

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