AIIMS2018Chemistry-Photoelectric Effect

AIIMS 2018 Chemistry Einstein's Photoelectric Equation MCQ Question

Type: MCQ-conceptual-Medium-Class 11

When on metal sheet fall λ1\lambda_1 light will eject electron with v1v_1 velocity and with λ2\lambda_2 light eject electron of v2v_2 velocity, what is v22v12v_2^2 - v_1^2 value

A

2hcm(1λ21λ1)\frac{2hc}{m}\left(\frac{1}{\lambda_2} - \frac{1}{\lambda_1}\right)

B

hcm(1λ21λ1)\frac{hc}{m}\left(\frac{1}{\lambda_2} - \frac{1}{\lambda_1}\right)

C

2hcm(1λ11λ2)\frac{2hc}{m}\left(\frac{1}{\lambda_1} - \frac{1}{\lambda_2}\right)

D

m2hc(1λ21λ1)\frac{m}{2hc}\left(\frac{1}{\lambda_2} - \frac{1}{\lambda_1}\right)

Correct Answer

Option B

Detailed Explanation

In the photoelectric effect, the kinetic energy (KE) of the emitted electrons is given by the equation KE=hcλϕKE = \frac{hc}{\lambda} - \phi, where ϕ\phi is the work function of the metal. For two wavelengths λ1\lambda_1 and λ2\lambda_2, the velocities v1v_1 and v2v_2 relate to their kinetic energies as KE1=12mv12KE_1 = \frac{1}{2}mv_1^2 and KE2=12mv22KE_2 = \frac{1}{2}mv_2^2. By equating the kinetic energies, we find that v22v12=2hcm(1λ21λ1)v_2^2 - v_1^2 = \frac{2hc}{m} \left( \frac{1}{\lambda_2} - \frac{1}{\lambda_1} \right), which corresponds to option B.

Options A and C incorrectly apply the factor of 2 or the order of λ1\lambda_1 and λ2\lambda_2, while option D misrepresents the relationship by introducing an incorrect factor. Understanding the derivation of kinetic energy from the photoelectric effect is crucial for solving such problems.

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