AIIMS2018Chemistry-Solutions

AIIMS 2018 Chemistry Normality and Molarity Assertion Reason Question

Type: Assertion Reason-conceptual-Medium-Class 12

Assertion: The normality of 0.3 M aqueous solution of H₃PO₄ is equal to 0.6 N. Reason: Equivalent weight of H₃PO₃ = Molecular weight of H₃PO₄3\frac{\text{Molecular weight of H₃PO₄}}{3}

A

If both assertion and reason are true and reason is the correct explanation of assertion.

B

If both assertion and reason are true but reason is not the correct explanation of assertion.

C

If assertion is true but reason is false.

D

If both assertion and reason are false.

Correct Answer

Option C

Detailed Explanation

The assertion is true because the normality (N) of a 0.3 M solution of H₃PO₄ is indeed 0.6 N, as phosphoric acid (H₃PO₄) can donate three protons (H⁺), making its equivalent concentration twice the molarity. However, the reason is false because the equivalent weight of H₃PO₄ is actually Molecular weight of H₃PO₄3\frac{\text{Molecular weight of H₃PO₄}}{3}, not H₃PO₃, which is a different compound (phosphorous acid). Options A and B are incorrect because they imply that the reason correctly explains the assertion, which it does not, and option D is incorrect as the assertion is true.

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