AIIMS 2018 Chemistry Normality and Molarity Assertion Reason Question
Assertion: The normality of 0.3 M aqueous solution of H₃PO₄ is equal to 0.6 N. Reason: Equivalent weight of H₃PO₃ =
If both assertion and reason are true and reason is the correct explanation of assertion.
If both assertion and reason are true but reason is not the correct explanation of assertion.
If assertion is true but reason is false.
If both assertion and reason are false.
Correct Answer
Detailed Explanation
The assertion is true because the normality (N) of a 0.3 M solution of H₃PO₄ is indeed 0.6 N, as phosphoric acid (H₃PO₄) can donate three protons (H⁺), making its equivalent concentration twice the molarity. However, the reason is false because the equivalent weight of H₃PO₄ is actually , not H₃PO₃, which is a different compound (phosphorous acid). Options A and B are incorrect because they imply that the reason correctly explains the assertion, which it does not, and option D is incorrect as the assertion is true.
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