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AIIMS2002Chemistry-Redox Reactions

AIIMS 2002 Chemistry Oxidizing and Reducing Agents Assertion Reason Question

Type: Assertion Reason-conceptual-Medium-Class 11

Assertion : Stannous chloride gives grey precipitate with mercuric chloride, but stannic chloride does not do so.

Reason : Stannous chloride is a powerful oxidising agent which oxidises mercuric chloride to metallic mercury.

A

If both the assertion and reason are true and the reason is a correct explanation of the assertion.

B

If both the assertion and reason are true but the reason is not a correct explanation of the assertion.

C

If the assertion is true but the reason is false.

D

If both the assertion and reason are false.

Correct Answer

Option C

Detailed Explanation

The assertion states that stannous chloride (SnCl2) gives a grey precipitate with mercuric chloride (HgCl2), which is true. The grey precipitate is due to the formation of metallic mercury (Hg) when SnCl2 reduces HgCl2. However, the reason claims that stannous chloride is a powerful oxidizing agent that oxidizes mercuric chloride to metallic mercury, which is incorrect. In reality, SnCl2 acts as a reducing agent, not an oxidizing agent, as it donates electrons to HgCl2, reducing it to Hg. Therefore, the assertion is true, but the reason is false, making the correct answer C. Other options are incorrect because: A) both statements cannot be true; B) the reason is not a correct explanation; D) both cannot be false since the assertion is true.

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