AIIMS2019Chemistry-Haloalkanes and Haloarenes

AIIMS 2019 Chemistry SN1 and SN2 mechanisms Assertion Reason Question

Type: Assertion Reason-conceptual-Medium-Class 12

Assertion: CH3CCH3CH3OCH3\text{CH}_3 - \underset{\substack{| \\ \text{CH}_3}}{\overset{\substack{\text{CH}_3 \\ |}}{\text{C}}} - \text{O} - \text{CH}_3 React with HBr to form (CH3)3CBr(\text{CH}_3)_3\text{CBr} and CH3OH\text{CH}_3\text{OH}

Reason: It follows SN1 mechanism

Correct Answer

Option B

Detailed Explanation

Option B is correct because the assertion that (CH₃)₃CBr and (CH₃)₃OH are formed when reacting with HBr is true, as tertiary alcohols can undergo protonation and subsequent nucleophilic substitution. However, while the reaction follows an SN₁ mechanism, which involves the formation of a carbocation, the reason provided does not specifically explain the formation of both products, as (CH₃)₃OH is not a direct product of the reaction with HBr.

Option A is incorrect because, although both statements are true, the reason does not adequately explain the assertion. Option C is incorrect since the assertion is indeed true. Option D is incorrect because the reason is true; it just does not correctly explain the assertion.

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