AIIMS 2019 Chemistry SN1 and SN2 mechanisms Assertion Reason Question
Assertion: React with HBr to form and
Reason: It follows SN1 mechanism
If both assertion and reason are true and reason is the correct explanation of assertion.

If both assertion and reason are true but reason is not the correct explanation of assertion.

If assertion is true but reason is false.

If both assertion and reason are false.

Correct Answer
Detailed Explanation
Option B is correct because the assertion that (CH₃)₃CBr and (CH₃)₃OH are formed when reacting with HBr is true, as tertiary alcohols can undergo protonation and subsequent nucleophilic substitution. However, while the reaction follows an SN₁ mechanism, which involves the formation of a carbocation, the reason provided does not specifically explain the formation of both products, as (CH₃)₃OH is not a direct product of the reaction with HBr.
Option A is incorrect because, although both statements are true, the reason does not adequately explain the assertion. Option C is incorrect since the assertion is indeed true. Option D is incorrect because the reason is true; it just does not correctly explain the assertion.
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