AIIMS2018Chemistry-Acid-Base Reactions

AIIMS 2018 Chemistry Salt Hydrolysis Assertion Reason Question

Type: Assertion Reason-conceptual-Medium-Class 11

Assertion: Na₂SO₃ solution give basic solution in litmus solution Reason: It react with water and H₂SO₃ form

A

If both assertion and reason are true and reason is the correct explanation of assertion.

B

If both assertion and reason are true but reason is not the correct explanation of assertion.

C

If assertion is true but reason is false.

D

If both assertion and reason are false.

Correct Answer

Option B

Detailed Explanation

The assertion is true because Na₂SO₃ (sodium sulfite) dissociates in water to produce hydroxide ions (OH⁻), resulting in a basic solution that turns litmus paper blue. The reason is also true, as Na₂SO₃ reacts with water to form H₂SO₃ (sulfurous acid), but this reaction does not directly explain the basicity of the solution; rather, it is the formation of hydroxide ions that accounts for the basic nature. Options A and C are incorrect because while both statements are true, the reason does not correctly explain the assertion, and option D is incorrect as both statements are indeed true.

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