AIIMS 2018 Chemistry Le Chatelier's Principle MCQ Question
What happens on increasing pressure at constant temperature?
Rate of Haber process decreases
Solubility of gas increases in liquid
Solubility of solid increases in liquid
2C(s) + CO₂(g) → 2CO(g) reaction moves forward.
Correct Answer
Detailed Explanation
Increasing pressure at constant temperature favors the solubility of gases in liquids due to Le Chatelier's principle, which states that a system at equilibrium will adjust to counteract changes. Since gas molecules occupy more volume, increasing pressure shifts the equilibrium towards the dissolved state, enhancing solubility. In contrast, option A is incorrect because the Haber process (N₂(g) + 3H₂(g) ⇌ 2NH₃(g)) is favored by high pressure, making the rate increase, not decrease. Option C is incorrect as the solubility of solids in liquids is generally unaffected by pressure, and option D is incorrect because the reaction 2C(s) + CO₂(g) → 2CO(g) would shift left, favoring the formation of solid carbon (C) under increased pressure.
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