AIIMS2014Chemistry-Buffers

AIIMS 2014 Chemistry Buffers MCQ Question

Type: MCQ-conceptual-Medium-Class 11

In a basic buffer, 0.0025 mole of NH4Cl and 0.15 mole of NH4OH are present. The pH of the solution will be (pKa) = 4.74.

A

11.04

B

10.24

C

6.62

D

5.48

Correct Answer

Option A

Detailed Explanation

The correct answer is A) 11.04 because in a basic buffer solution, the pH can be calculated using the Henderson-Hasselbalch equation: pH = pKa + log([base]/[acid]). In this case, NH4OH acts as the base and NH4Cl provides the conjugate acid (NH4+). With the given concentrations, we find that the pH is significantly higher than 7, resulting in a pH of approximately 11.04, indicating a basic solution.

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