AIIMS2011Chemistry-Coordination Chemistry

AIIMS 2011 Chemistry Ligand Field Theory MCQ Question

Type: MCQ-conceptual-Medium-Class 12

The wavelength of light absorbed is shortest in

A

[Co(NH₃)₅Cl]²⁺

B

[Co(NH₃)₅H₂O]³⁺

C

[Co(NH₃)₆]³⁺

D

[Co(en)₃]³⁺

Correct Answer

Option A

Detailed Explanation

As in complex [Co(NH3)6]3+ unpaired electrons are present, so it requires less energy for excitation. Thus, the wavelength of light absorbed will be highest (i.e., E ∝ 1/λ).

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