AIIMS2019Chemistry-Periodic Table

AIIMS 2019 Chemistry Ionization Energy Assertion Reason Question

Type: Assertion Reason-conceptual-Medium-Class 11

Assertion: Ionisation enthalpy of beryllium is higher than that of boron.

Reason: Across the period, from left to right, ionization enthalpy decreases.

A

If both assertion and reason are true and reason is the correct explanation of assertion.

B

If both assertion and reason are true but reason is not the correct explanation of assertion.

C

If assertion is true but reason is false.

D

If both assertion and reason are false.

Correct Answer

Option C

Detailed Explanation

Option C is correct because the assertion that the first ionization energy of beryllium (Be) is greater than that of boron (B) is true; however, the reason provided is incorrect. Beryllium has a stable electron configuration (1s² 2s²), but its higher ionization energy compared to boron (1s² 2s² 2p¹) is primarily due to its smaller atomic radius and increased effective nuclear charge, which leads to stronger attraction between the nucleus and the outermost electron.

Option A is incorrect because, while the assertion is true, the reason does not accurately explain the phenomenon. Option B is also incorrect because it claims that the reason is not the correct explanation when, in fact, it is incorrect altogether. Option D is incorrect as the assertion is indeed correct.

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