AIIMS 2019 Chemistry Ionization Energy Assertion Reason Question
Assertion: Ionisation enthalpy of beryllium is higher than that of boron.
Reason: Across the period, from left to right, ionization enthalpy decreases.
If both assertion and reason are true and reason is the correct explanation of assertion.
If both assertion and reason are true but reason is not the correct explanation of assertion.
If assertion is true but reason is false.
If both assertion and reason are false.
Correct Answer
Detailed Explanation
Option C is correct because the assertion that the first ionization energy of beryllium (Be) is greater than that of boron (B) is true; however, the reason provided is incorrect. Beryllium has a stable electron configuration (1s² 2s²), but its higher ionization energy compared to boron (1s² 2s² 2p¹) is primarily due to its smaller atomic radius and increased effective nuclear charge, which leads to stronger attraction between the nucleus and the outermost electron.
Option A is incorrect because, while the assertion is true, the reason does not accurately explain the phenomenon. Option B is also incorrect because it claims that the reason is not the correct explanation when, in fact, it is incorrect altogether. Option D is incorrect as the assertion is indeed correct.
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