AIIMS 2019 Chemistry Zero Order Reactions MCQ Question
Assertion: If in zero order reaction, the concentration of the reactant is doubled, the half-life period is also doubled.
Reason: For a zero order reaction, the rate of the reaction is independent of initial concentration.
If both assertion and reason are true and reason is the correct explanation of assertion.
If both assertion and reason are true but reason is not the correct explanation of assertion.
If assertion is true but reason is false.
If both assertion and reason are false.
Correct Answer
Detailed Explanation
In a zero-order reaction, the half-life (t₁/₂) is given by the equation , where is the initial concentration of the reactant and is the rate constant. When the concentration is doubled, the new half-life becomes , indicating that the half-life is indeed doubled, thus supporting option B.
Option A is incorrect because the half-life is not halved; option C is also incorrect since the half-life does change with concentration; option D is irrelevant as option B is valid. This illustrates that in zero-order kinetics, the half-life is directly proportional to the initial concentration of the reactant.
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