AIIMS2008Chemistry-Chemical Kinetics

AIIMS 2008 Chemistry Rate Laws MCQ Question

Type: MCQ-numerical-Medium-Class 12

For the reaction, 2NO₂ + F₂ → 2NO₂F, following mechanism has been provided. NO₂ + F₂ → Slow → NO₂F + F NO₂ + F → Fast → NO₂F Thus, rate expression of the above reaction can be written as

A

r = k [NO₂]₂[F₂]

B

r = k [NO₂][F₂]

C

r = k [NO₂]

D

r = k [F₂]

Correct Answer

Option B

Detailed Explanation

Slowest step of mechanism decides the rate expression.

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