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AIIMS2018Chemistry-Chemical Bonding and Molecular Structure

AIIMS 2018 Chemistry Molecular Orbital Theory MCQ Question

Type: MCQ-conceptual-Medium-Class 11

Which contain at least one e−\text{e}^- in σ2p\sigma 2\text{p} bonding MO

A

O2\text{O}_2

B

B2\text{B}_2

C

C2\text{C}_2

D

Li2\text{Li}_2

Correct Answer

Option A

Detailed Explanation

O₂ is paramagnetic because it has two unpaired electrons in its π*2p antibonding molecular orbitals, which allows it to be attracted to a magnetic field. In contrast, O₂ is not diamagnetic (B) since diamagnetic substances have all electrons paired. The bond order of O₂ is calculated as (number of bonding electrons - number of antibonding electrons) / 2, resulting in a bond order of 2, making options C and D incorrect, as bond orders of 3 and 1 do not accurately reflect the molecular structure of O₂.

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