AIIMS2018Chemistry-Chemical Bonding

AIIMS 2018 Chemistry Molecular Geometry MCQ Question

Type: MCQ-conceptual-Medium-Class 11

Which molecule pair do not have identical structure

A

I3\text{I}_3^-, BeF2\text{BeF}_2

B

HClO\text{HClO}, SO2\text{SO}_2

C

BF3\text{BF}_3, ICl3\text{ICl}_3

D

BrF4\text{BrF}_4^-, XeF4\text{XeF}_4

Correct Answer

Option C

Detailed Explanation

Boron trifluoride (BF₃) exhibits a trigonal planar geometry due to its three bonding pairs of electrons and no lone pairs on the boron atom, resulting in a bond angle of 120°. In contrast, iodine trichloride (ICl₃) has a T-shaped geometry because it has three bonding pairs and two lone pairs of electrons on the iodine atom, leading to a distorted arrangement that minimizes electron pair repulsion. Other options may refer to incorrect molecular geometries or configurations that do not accurately represent the shapes of BF₃ or ICl₃. Understanding the VSEPR (Valence Shell Electron Pair Repulsion) theory is crucial for predicting molecular shapes based on electron pair arrangements.

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