AIIMS2012Chemistry-Aromatic Compounds

AIIMS 2012 Chemistry Electrophilic Substitution Assertion Reason Question

Type: Assertion Reason-conceptual-Medium-Class 11

Assertion : Phenol is more reactive than benzene towards electrophilic substitution reaction. Reason : In the case of phenol, the intermediate carbocation is more resonance stabilised.

A

If both assertion and reason are true and reason is the correct explanation of assertion

B

If both assertion and reason are true but reason is not the correct explanation of assertion

C

If assertion is true but reason is false

D

If both assertion and reason are false

Correct Answer

Option B

Detailed Explanation

OH group shows +M effect and is an activating group. Hence the orientation for phenolic substitution is more stable.

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