AIIMS2019Chemistry-Aldehydes and Ketones
AIIMS 2019 Chemistry Tollen's Test MCQ Question
Type: MCQ-conceptual-Medium-Class 12
Above compounds can be differentiated by following reagent:

A
2-4DNP (Bradyreagent)
B
Tollen's reagent
C
Lucas reagent
D
Correct Answer
Option B
Detailed Explanation
Acetals do not give a positive Tollen’s test because they lack a free aldehyde or ketone functional group, which is necessary for the reduction of silver ions (Ag⁺) to metallic silver (Ag) in the presence of Tollen's reagent. Instead, acetals are stable and do not react under these conditions, leading to a negative result. Other options are not applicable as they do not pertain to the question's context regarding the chemical behavior of acetals with Tollen's reagent.
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